LESCO -- GRANULAR FERTILIZER ======================================================= MSDS Safety Information ======================================================= FSC: 6840 MSDS Date: 12/13/1993 MSDS Num: CBHCQ LIIN: 00N068130 Product ID: GRANULAR FERTILIZER MFN: 01 Responsible Party Cage: 1A311 Name: LESCO Address: 20005 LAKE RD City: ROCKY RIVER OH 44116 Info Phone Number: 216-333-9250 Emergency Phone Number: 216-333-9250;800-424-9300(CHEMTREC) Published: Y ======================================================= Contractor Summary ======================================================= Cage: 1A311 Name: LESCO Address: 20005 LAKE RD City: ROCKY RIVER OH 44116 Phone: 216-333-9250 ======================================================= Ingredients ======================================================= Cas: 57-13-6 RTECS #: YR6250000 Name: UREA OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 9011-05-6 RTECS #: YU1610000 Name: UREA, POLYMER W/FORMALDEHYDE; (UREAFORM) OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 7783-28-0 Name: AMMONIUM PHOSPHATE; (DIAMMONIUM PHOSPHATE) OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 7447-40-7 RTECS #: TS8050000 Name: POTASSIUM CHLORIDE OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 7778-80-5 RTECS #: TT5900000 Name: POTASSIUM SULFATE (2:1) OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 7782-63-0 RTECS #: NO8510000 Name: IRON (II) SULFATE (1:1), HEPTAHYDRATE; (IRON SULFATE) (CERCLA) OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS ------------------------------ Cas: 7487-88-9 RTECS #: OM4500000 Name: MAGNESIUM SULFATE (1:1) OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 7785-87-7 RTECS #: OP1050000 Name: MANGANESE (II) SULFATE (1:1) OSHA PEL: 5.0 MG/M3 (MN), CL ACGIH TLV: 5.0 MG/M3 (MN) ------------------------------ Cas: 1309-37-1 RTECS #: NO7400000 Name: IRON (III) OXIDE; (IRON OXIDE) OSHA PEL: 10 MG/M3 (FE) ACGIH TLV: 5 MG/M3 FUME (FE) ------------------------------ Cas: 1317-35-7 RTECS #: OP0895000 Name: MANGANESE OXIDE OSHA PEL: 5 MG/M3 (MN), C ACGIH TLV: 5 MG/M3 (MN) ------------------------------ Cas: 14977-37-8 Name: SULFATES; (SULFATE OF POTASH MAGNESIA) OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ----------------------------- Cas: 471-34-1 RTECS #: FF9335000 Name: CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE) OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 39409-82-0 Name: MAGNESIUM CARBONATE OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ------------------------------ Cas: 7704-34-9 RTECS #: WS4250000 Name: SULFUR OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N) ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: LD50: (ORAL, RAT) >10,000 MG/KG Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: YES Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: ACUTE: MAY CAUSE MILD IRRITATION TO SKIN AND EYES. INGESTION OF LARGE AMOUNTS MAY CAUSE GASTROINTESTINAL DISORDER, NAUSEA, VOMITING AND/OR DIARRHEA. Explanation Of Carcinogenicity: NOT RELEVANT Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER. First Aid: EYES: FLUSH WITH CLEAR WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: REMOVE CONTAMINATED CLOTHING AND WASH AFFECTED AREA WITH SOAP AND WATER. INHAL: REMOVE TO FRES H AIR. INGEST: DRINK WARM WATER AND INDUCE VOMITING BY TOUCHING BACK OF THROAT WITH FINGER. CONSULT MD. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: IF MATERIAL IS NOT CONTAMINATED, SCOOP INTO CLEAN CONTAINER FOR USE. IF CONTAMINATED, SCOOP INTO CONTAINERS FOR DISPOSAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: DISPOSE ACCORDING TO FEDERAL EPA PROCEDURES AS OUTLINED IN RCRA AND FOLLOW STATE AND LOCAL GUIDELINES. BE SURE THAT CONTAINERS ARE COMPLETELY EMPTY BEFORE DISPOSAL. Handling And Storage Precautions: STORE IN COOL, DRY PLACE IF POSSIBLE. SEPARATE FROM PESTICIDES, FERTILIZERS, SEED, FEED, FOODSTUFFS & AWAY FROM DRAINS, SEWERS & WATER SOURCES. Other Precautions: DO NOT EAT, DRINK OR SMOKE WHEN HNDLG THIS PROD. KEEP OUT OF REACH OF CHILDREN. PRACTICE GOOD CARE & GOOD SAFETY PRECAUTIONS WHEN HNDLG THIS PROD. AVOID CNTCT W/EYES, SKIN & CLTHG. AVOID BRTHG DUST. D O NOT SWALLOW. WASH THORO AFTER HNDLG. ======================================================= Fire and Explosion Hazard Information ======================================================= Extinguishing Media: WATER SPRAY. Fire Fighting Procedures: USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP N). DO NOT BREATHE FUMES. REMOVE FROM AREA OF FIRE AT FIRST OPPORTUNITY. PVNT WATER RUNOFF FROM (SUPDAT) Unusual Fire/Explosion Hazard: IF HEATED TO DECOMP, WILL GIVE OFF TOX FUMES OF AMMONIA & FORMALDEHYDE. UNDER FIRE CONDITIONS, UREA MAY DECOMPOSE TO CYANURIC ACID, BIURET/AMMONIA. (SUPDAT) ======================================================= Control Measures ======================================================= Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). Ventilation: SUFFICIENT VENTILATION. Protective Gloves: IMPERVIOUS GLOVES. Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N). Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). IMPERVIOUS BOOTS, CLEAN CLOTHING, DUST MASK. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health: FIRE FIGHT PROC: ENTERING DRAINS, SEWERS OR WATER SOURCES. FERTILIZER WILL BECOME SLIPPERY WHEN WET. GUARD AGAINST FALLS. EXPLO HAZ: DISPERSION OF FINE DUST IN AIR MAY FORM EXPLO MIX. HAZ DECOMP PROD: IRON, POTASSIUM & PHOSPHORUS. UREA CANYIELD CYANURIC ACID OR BIURET UPON HEATING. ======================================================= Physical/Chemical Properties ======================================================= Solubility in Water: MODERATE Appearance and Odor: MULTICOLORED GRANULES; SLIGHT PUNGENT ODOR. ======================================================= Reactivity Data ======================================================= Stability Indicator: YES Stability Condition To Avoid: NONE KNOWN. Materials To Avoid: STRONG ACIDS, CAUSTIC COMPOUNDS, HUMID-WET CONDITIONS. Hazardous Decomposition Products: IF HEATED TO DECOMP, MAY GIVE OFF AMMONIA & FORMALDEHYDE AS WELL AS OXIDES OF SULFUR, MANGANESE, MAGNESIUM, (SUPDAT) Hazardous Polymerization Indicator: NO Conditions To Avoid Polymerization: NOT RELEVANT ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= HAZCOM Label ======================================================= Product ID: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.